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The syntheses, structures and magnetic properties of a host of polymetallic 3d transition‐metal clusters made with the pro‐ligand benzotriazole (BtaH) and its analogues are reported. These range from a family of tetradecametallic clusters with spin ground states as large as S ≈ 25, to decametallic vanadium “boxes”, to iron and manganese tetra‐ and super‐tetrahedra, to hexaicosametallic manganese single‐molecule magnets. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)
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Collison et al. (2006) studied this question.
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