The electronic absorption and reflectance properties of CuTCNQ and AgTCNQ have been studied in the visible and near infrared region. AgTCNQ exhibits spectra characteristic of an infinite diadic TCNQ chàin, while CuTCNQ shows an additional absorption overlapping with the low energy intramolecular transition. It was observed that the charge transfer band shows a particle size dependence.
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Kamitsos et al. (1986) studied this question.
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