Calculation of Coulomb-potential differences for nonequivalent atomic sites and comparison with the reported experimental x-ray-photoemission splittings, combined with a comparison of the valence electronic structure with that of other TCNQ salts, show that the degree of charge transfer in TTF-TCNQ is not unequivocally determined by photoemission spectroscopy.
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Epstein et al. (1975) studied this question.
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