Sedimentation of substitutional atoms and phase change in an In-Pb alloy under an ultrastrong gravitational field

It was found that an atomic-scale graded structure was formed, and a phase change occurred, in an In–Pb alloy by the sedimentation of substitutional solute atoms under an ultrastrong gravitational field (820 000 g (maximum); 150°C; 100 h). Continuous gradients in the concentration of Pb (from about 6 to 45 at.%) and In (from about 94 to 55 at.%) and resulting changes in the lattice constant were observed. Fcc (Pb-rich) and tetragonal (In-rich) phases appeared in the strong- and weak-gravity regions respectively from a single starting fct α phase. It is suggested that sedimentation of substitutional atoms can be used to control the compositions and structure of bulk materials and also thin films or layer interfaces.