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Cationic palladium imine−phosphine complexes [Pd(P−N)(CH 3 )(CH 3 CN)] + catalyze the living block polymerization and copolymerization of olefins and/or carbon monoxide. The palladium-capped polymers, intermediates of the polymerization, were isolated.
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Chen et al. (2001) studied this question.
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