An Aldol-Based Approach to the Asymmetric Synthesis of l -Callipeltose, the Deoxyamino Sugar of l -Callipeltoside A

[reaction: see text] The L-callipeltose subunit of L-callipeltoside A has been synthesized in 10 steps and 13% overall yield from D-threonine. The key steps are a highly diastereoselective Felkin anti aldol addition to a methyl ketone and a selective methylation of a secondary alcohol in the presence of a secondary carbamate.