Transition metal complexes of alkyl trithiocarbonates (thioxanthates) have not received as much attention as have complexes with other monoanionic 1,1-dithiolates. Structural information about copper thioxanthates has not been reported. Edwald and Sinn1 reported the preparation of Cu(II) thioxanthate but did not characterize nor isolate the dark-colored compound. Duncan, Ott, and Reid2 studied the reaction of polymeric cuprous mercaptides with carbon disulfide in 1931 and reported the reddish-brown products as cuprous thioxanthates [Cu1(RSCS2)].
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Avdeef et al. (1975) studied this question.
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