The absorption spectra and vapor pressures of the hydrogen and deuterium bromides have been measured. The frequency difference between the absorption curves of these compounds is about three times as great as can be accounted for by the zero-point energy differences. Theoretical reasons for this effect are discussed. The vapor pressures are almost identical. The application of Trouton's rule to isotopic compounds is discussed and calculated values for the constant are presented.
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Bates et al. (1935) studied this question.
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