BCl(A-X) band emission peaked at 272 nm plus N2(C-B) spectra from dc breakdown initiated detonations in HN3/BCl3 gas mixtures are reported. Negligible NH(A-X) emission at 336.0/337.1 nm is observed in contrast to its strong intensity in pure HN3 breakdown-induced decomposition. The presence of the HN3 detonation appears to enhance the production of BCl(A-X) emission indicating the liberation of chemical energy from the HN3 decomposition to excited BCl but at low effective yields of 8×10−4%.
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Wright et al. (1993) studied this question.
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