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Photocrosslinkable poly(2‐vinyloxyethyl cinnamate)'s with substituents in para position of cinnamoyl moieties were prepared cationically. Polymerizability of the monomers was markedly governed by the substituent and the glass transition temperatures of the polymers varied in the range of about 0 to 72°C. The photocrosslinking mechanism in relation to the photosensitivity of the polymers is discussed on the basis of spectroscopical studies.
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Watanabe et al. (1984) studied this question.
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