Geminate recombination has been previously suggested in the photochemistry of several ions in solution, namely, the halides, phenolate ferrocyanide and thiocyanate. It is demonstrated that in the concentration range studied, the observed dependence of the quantum yield on scavenger concentrations is due to homogeneous competition between the scavenger and a product or rational intermediates, rather than to cage scavenging competing with geminate recombination.
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Czapski et al. (1968) studied this question.
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