Spontaneous disproportionation of lithium biphenyl radical anion into a lithium biphenyl dianion plus neutral biphenyl, according to 2LiBiph ⇄ Li 2 Biph + Biph, has been evidenced experimentally by UV-vis spectroscopy and backed up theoretically using TDDFT methods.
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Bondarchuk et al. (2018) studied this question.
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