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A two-way street! The two-electron oxidation of a novel binuclear stibine gold compound induces an umpolung of the SbAu dative bond which switches from Sb→Au in the reduced state to Sb←Au in the oxidized state (see scheme). This reversible process can be triggered by the addition/elimination of a halogen-molecule equivalent.
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Wade et al. (2011) studied this question.
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