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Diglycosyl Derivatives. Preliminary communication Novel types of diglycosyl compounds, some of them bearing a resemblance to natural di‐ or tri‐saccharides are described: a diglycosyldiyne (1), a diglycosylthiophene (2), a diglycosylaziridine (3), a diglycosyldioxolane (4), as well as six C,N‐diglycosylnitrones, 9b–9f and 14. These C,N‐diglycosylnitrones, on treatment with an acetylenic Grignard reagent, led to the expected acetylenic diglycosyl‐hydroxylamine 11, whereas diglycosylisoxazolines (f. ex. 10) were obtained when these nitrones underwent 1,3‐dipolar cycloaddition to acetylenic compounds.
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Tronchet et al. (1979) studied this question.
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