The ultralow thermal conductivity, κ, observed experimentally in intentionally roughened silicon nanowires (SiNWs) is reproduced in phonon Monte Carlo simulations with exponentially correlated real-space rough surfaces similar to measurement [J. Lim et al., Nano Lett. 12, 2475 (2012)]. Universal features of thermal transport are revealed by presenting κ as a function of the normalized geometric mean free path λ¯ (0<λ¯<1); the diffusive (Casimir) limit corresponds to λ¯=1/2. κ vs λ¯ is exponential at low-to-moderate roughness (high λ¯), where internal scattering randomly interrupts phonon bouncing across the SiNW, and linear at high roughness (low λ¯), where multiple scattering events at the same surface results in ultralow, amorphous-limit thermal conductivity.
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Maurer et al. (2015) studied this question.
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