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Pure silver chloride crystals, when cooled rapidly from high temperatures, show enhanced ionic conductivity which may be attributed to quenched-in Schottky defects. From the annealing out of this extra conductivity one deduces that for an associated vacancy pair the binding energy is 0.42 ev and the migration energy is ≥1.0 ev. The decorability of interior dislocations by swept-in photoelectrons is also discussed and is shown to be sensitive to the purity of the crystal.
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Layer et al. (1962) studied this question.
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