The CS 2 adduct of “iridabenzene” undergoes dimerization and cyclotrimerization reactions by linking subunits through thiocarbonyl sulfur centers. The cyclotrimerization product (compound 4 ) has been structurally characterized and contains a novel organometallic trithia-12-crown-3 ring system.
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Bleeke et al. (1997) studied this question.
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