C−C Coupling of the Alkynyl and Alkenyl Fragments of Os(C2CO2CH3){CHCHC(O)OCH3}(CO)(PiPr3)2 by Action of HCl: The Vinylidene [Os{CHCHC(O)OCH3}(CCHCO2CH3)(CO)(PiPr3)2]BF4 as Intermediate | Synapse

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Synapse has enriched 10 related papers. Consider them for comparative context:

1Organometallic chemistry of vinylidene and related unsaturated carbenesOriginal Research · 1991 · 1,080 citations
2Molecular orbital study of bonding, conformations, and reactivity of transition-metal complexes containing unsaturated organic ligands. Electrophilic and nucleophilic additions to acetylide, vinylidene, vinyl, and carbene ligandsOriginal Research · 1982 · 237 citations
3Synthesis, structure, and alkylation of chiral vinylrhenium complexes (.eta.5-C5H5)Re(NO)(PPh3)(CX:CHR) (X = H, OCH3). A mechanistic study of 1,3-asymmetric induction from rhenium to carbonOriginal Research · 1987 · 62 citations
4Reactions of the Dihydrogen Complex OsCl2(.eta.2-H2)(CO)(PiPr3)2 with Terminal Alkynes: Synthesis of Carbene, Vinylcarbene, and .mu.-Bis-carbene Osmium (II) DerivativesOriginal Research · 1995 · 115 citations
5Synthesis and reactivity of [OsH{C6H4(CHCHH) }(CO)(PPri3)2] and the formato compounds [Os{(E )-CHCHPh}(η2-O 2CH)(CO)(PPri3)2] and [OsH(η2-O2CH)(CO)(PPri3) 2]*Original Research · 1997 · 31 citations
6The Os(CO)(PiPr3)2 Unit as a Support for the Transformation of Two Alkyne Molecules into New Organometallic LigandsOriginal Research · 1997 · 58 citations
7Synthesis and Characterization of Ruthenium−Osmium Complexes Containing μ-Bisalkenyl, μ-Alkenylvinylidene, and μ-Alkenylcarbene Bridge LigandsOriginal Research · 1999 · 46 citations
8Structure and H<sub>2</sub>-Loss Energies of OsHX(H<sub>2</sub>)(CO)L<sub>2</sub> Complexes (L = P(<i>t</i>-Bu)<sub>2</sub>Me, P(<i>i</i>-Pr)<sub>3</sub>; X = Cl, I, H): Attempted Correlation of <sup>1</sup><i>J</i>(H−D), <i>T</i><sub>1min</sub>, and Δ<i>G</i><sup>⧧</sup>Original Research · 1996 · 80 citations
9Architecturally Distinctive Chiral-at-Rhenium Complexes with P═O/N:, P═O/P═O and S═O/S═O Donor Moieties: Syntheses, Structures, Reactivity, and Gas Phase Brønsted BasicitiesOrganometallics · 2026
10Flash Communication: Cooperative C–Cl Bond Activation of Dichloromethane by Heterobimetallic Ir(I)–M(IV) Pairs (M = Mo, W)Organometallics · 2026

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