The hexahydride OsH 6 (P i Pr 3 ) 2 reacts with cyclohexylmethyl ketone to give the trihydride which has been characterized by X-ray diffraction analysis. In solution, the hydride ligands of this complex undergo two different thermally activated exchange processes. Two of them also show weak quantum exchange coupling.
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Barrio et al. (2001) studied this question.
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