Experimental data on photothermal ionization spectroscopy of hydrogen-related acceptors in ultrapure germanium are presented. Ground levels do not split under applied uniaxial stresses. A theoretical model based on dynamic tunneling of hydrogen is proposed and analyzed in detail. An overall chemical picture of impurities associated with hydrogen-acceptors and donors-is also presented. It accounts consistently for all known facts related to these complexes: infrared spectra, thermal annealing and quenching, and conditions of crystal growth.
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Häller et al. (1980) studied this question.
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