The two-electron oxidation of 1,2-bis(ruthenocenyl)ethynes and bis(1',2',3',4',5'-pentamethylruthenocenyl)ethynes, prepared from alkyne metathesis of the corresponding propynes, gave the unprecedented mu 2-eta 6:eta 6-bis(cyclopentadienylidene)ethene diruthenium complexes.
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Satô et al. (2002) studied this question.
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