Very thin sulfide films emit light only on alternate half-cycles of the voltage sine wave, whereas the emission of thicker films and phosphor powders is quite symmetrical with polarity. This asymmetry of emission, together with clipping or dc bias of the applied voltage, is used to confirm unambiguously that the excitation and recombination steps in electroluminescence are separable and occur sequentially and under different field configurations, and that the recombination is field-driven.
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William A. Thornton (1961) studied this question.
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