Unique Proton Dynamics in an Efficient MOF-Based Proton Conductor

Recently, research on metal–organic frameworks (MOFs) serving as a new type of proton conductive material has resulted in many exciting achievements. However, direct observation of a well-established proton-transfer mechanism still remains challenging in MOFs and other crystalline compounds, let alone other conductive materials. Herein we report the solvothermal synthesis of a new proton-conducting MOF, (Me 2 NH 2 )[Eu(L)] (H 4 L = 5-(phosphonomethyl)isophthalic acid). The compound consists of a layered anionic framework [Eu(L)] − and interlayer-embedded counter cations (Me 2 NH 2 ) +, which interact with adjacent uncoordinated O atoms of phosphonate groups to form strongly (N–H···O) hydrogen-bonded chains aligned parallel to the c -axis. Facile proton transfer along these chains endows the compound with single-crystal anhydrous conductivity of 1.25 × 10 –3 S·cm –1 at 150 °C, and water-assisted proton conductivity for a compacted pellet of microcrystalline crystals attains 3.76 × 10 –3 S·cm –1 at 100 °C and 98% relative humidity (RH). Proton dynamics (vibrating and transfer) within N–H···O chains of the compound are directly observed using a combination of anisotropic conductivity measurements and control experiments using large single-crystals and pelletized samples, in situ variable-temperature characterization techniques including powder X-ray diffraction (PXRD), single-crystal X-ray diffraction (SCXRD), diffuse reflectance infrared Fourier transform spectrum (DRIFTS), and variable-temperature photoluminescence. In particular, a scarce single-crystal to single-crystal (SCSC) transformation accompanied by proton transfer between an anionic structure (Me 2 N H 2 )[Eu(L)] and an identical neutral framework [Eu( H L)] has been identified.