The compounds SrPu 2 Ti 4 O 12 , Pu 2 Ti 3 O 8.79 , and Pu 2 Ti 2 O 7 , where plutonium is in the (III) oxidation state, were prepared and identified via X‐ray diffraction (XRD). The solid solubility limit of Pu 2 Ti 2 O 7 in Ln 2 Ti 2 O 7 (Ln = Gd, Er, or Lu) was also studied via XRD; it was determined that the solubility of Pu 2 Ti 2 O 7 increased as the radius of the lanthanide ion in the host compound decreased. Attempts to synthesize Sr 2 Pu 2 Ti 5 O 16 and Sr 2 Ce 2–y Pu y Ti 5 O 16 solid solutions, where plutonium is in the (IV) oxidation state, were unsuccessful.
No takes yet. Share an insight, caveat, or question.
Shoup et al. (1996) studied this question.
Synapse has enriched 5 related papers. Consider them for comparative context: