Electrochemical oxidation of the solution containing benzo[c]phenothiazine (B[c]PT) and dicyanophthalocyaninatocobalt(iii) anion, [Co(Pc)(CN)2 ]– , gives crystalline solids containing cyano-bridged cobalt–phthalocyanine dimer units. The dimeric species which may exist in equilibrium with the monomer is selectively trapped by crystallization with the B[c]PT cation radical.
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Takano et al. (1998) studied this question.
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