We review the use of the contactless methods of photoreflectance (PR), contactless electroreflectance (CER) and wavelength modulated differential surface photovoltage spectroscopy (DSPS) for the nondestructive, room temperature characterization of a wide variety of wafer‐scale III–V semiconductor device structures. Some systems that will be discussed include heterojunction bipolar transistors (including the determination of the built‐in fields/doping levels in the emitter and collector regions, alloy composition, and dc current gain factor), pseudomorphic GaAlAs/InGaAs/GaAs high electron mobility transistors (including the determination of the composition, width, and two‐dimensional electron gas density in the channel), InGaAsP/InP quantum well edge emitting lasers (including the detection of p‐dopant interdiffusion), vertical‐cavity surface‐emitting lasers (determination of fundamental conduction to heavy‐hole excitonic transition and cavity mode). (© 2005 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
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