Infrared bands associated with the (HCl)*(H 2 SO 4 ) complex were identified in argon matrices. In agreement with computation (Beichert, P.; Schrems, O. J. Phys. Chem. A 1998, 102, 10540), HCl is found to bridge between the OH and S O groups of the H 2 SO 4 monomer, but the hydrogen-bonded O H and Cl H stretches are more red shifted than predicted. No spectral evidence for the existence of an (HCl)*(SO 3 ) complex was found.
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Givan et al. (2000) studied this question.
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