Capillary experiments of flow induced crystallization of HDPE

Flow‐induced crystallization experiments are made in a capillary apparatus modified with a downstream reservoir under pressure. Capillary length, diameter, and entrance angle are changed, as well as flow rate. The results show that the crystallization temperature is influenced both by the elongational flow at the capillary entrance and by the shear flow along the capillary. The independent effect of the pressure equals that obtained under static conditions. The effect of shear is correlated in terms of shearing work.