Gas-phase observation of C60(1-), C60(3-), and C60(4-) anions generated at platinum and gold electrodes and detected by electrochemical/electrospray mass spectrometry is reported. The anions were electrochemically generated from solutions of C60 dissolved in toluene/acetonitrile as well as from reduction of C60 films on gold electrode surfaces. The gas-phase observation of C60(3-) and C60(4-), despite the fact that they have negative electron affinities, is a result of a Coulombic barrier to electron loss. The fact that C60(2-) was not detected in these experiments is ascribed to its limited solubility under the reaction conditions. These studies, which demonstrate the gas-phase kinetic stability of C60(3-) and C60(4-), illustrate the promise of electrochemical/electrospray mass spectrometry for the study of metastable anions.
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Cammarata et al. (2005) studied this question.
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