The crystal structures of pyridiniodithioacetate (pydta) 1 and its first stable metal complex, [Cd(pydta)2Cl2] 2, have been determined; intermolecular C–H⋯S hydrogen bonds play a dominant role in determining the molecular packing of both structures, and 2 is further stabilized by the presence of weak C–H⋯Cl interactions.
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Wu et al. (2003) studied this question.
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