Reduced and reoxidized: Thin films (100 nm) of tetrakis(thiadiazole)porphyrazine (see picture) are highly ordered in an unusual orientation of the molecular planes owing to the strong self-assembling ability of these crystals. Electrochemical reduction of the thin films induces reversible electrochromism and n-type carrier doping.
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Miyoshi et al. (2007) studied this question.
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