Temperature dependence of ecl efficiency (η) and that of phosphorescence quantum yield(φp) of tris(bipyridine)Ru(II)-acetonitrile system have been investigated. Both η and φp increased with lowering temperature, while the ratio η⁄φp remained nearly constant. The value of η reached ca. 7 % at 0°C. Based on these results the ecl generation mechanism is discussed.
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Itoh et al. (1979) studied this question.
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