Key points are not available for this paper at this time.
A high-nitrogen compound (N10 structure), 1,1′-azobis(5-methyltetrazole) which is relatively stable, was obtained by azo coupling reactions with three different oxidants such as trichloroisocyanuric acid (TCICA), sodium dichloroisocyanurate (SDIC) and tert-butyl hypochlorite (t-BuOCl). In particular, TCICA has been used for the first time to oxidize N–NH2 to the N–NN–N linkage. The structural elucidation of the title compound was made by spectral and X-ray crystallographic analyses. The new N10 linkage containing compound exhibits both relative thermal stability and physical stability.
Tang et al. (2012) studied this question.