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January 1, 1996Recueil des Travaux Chimiques des Pays-Bas

A new mechanistic model for hydride transfer related to the redox couple NADH/NAD+. Criticism on the quantum‐chemical MO approach

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Abstract

A mechanistic study of hydride transfer based on (simplified) NADH/NAD+ model systems is given. The new model originates from a classical mechanism generally indicated as being an intramolecular nucleophilic displacement reaction. There is some controversy with the results of quantum‐chemical calculations.

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H. M. BUCK (1996) studied this question.

synapsesocial.com/papers/6a911235cd6c08c0eacaf00f https://doi.org/10.1002/recl.19961150604

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