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High efficient Tb3Al5O12:Ce3+ (TAG:Ce3+) phosphors were prepared in a solid-state reaction method with various fluxes. The results show that addition of proper flux can decrease the phase-forming temperature of the TAG crystals and improve the morphology as well as enhance the photoluminescence of the phosphors greatly. High efficient and low color-temperature white light-emitting diodes (WLEDs) were fabricated with the TAG:Ce3+ phosphor. Good performances of the WLEDs indicate that a mixture of H3BO3 and LiF is an excellent flux for synthesis of TAG:0.04Ce3+ phosphor and is beneficial to the fabrication of high efficient WLEDs.
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Chen et al. (2007) studied this question.
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