Reaction of Me 2 Si(η 5 -Me 4 C 5 )( t BuN)TiCl 2 with lithium indenide and methyllithium in a one-pot fashion produces a chiral ansa -titanocene imido complex, which is an effective initiator for syndiospecific polymerization of MMA.
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Jin et al. (2001) studied this question.
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