Hybrid polyoxometalate-porphyrin copolymeric films are obtained by the electro-oxidation of zinc octaethylporphyrin (ZnOEP) and zinc 5,15-dipyridinium octaethylporphyrin (5,15-ZnOEP(py)(2)(2+)) in the presence of the polyoxometalate [MnMo(6)O(18){(OCH(2))(3)CNHCO(4-C(5)H(4)N)}(2)](3-) (Py-POM-Py). These films allow the photocatalytic reduction of Ag(I)(2)SO(4) under visible irradiation in air in the presence of propan-2-ol at the 2D interface between water and the copolymeric films. The formation of metallic Ag(0) nanowires and triangular nanosheets is observed.
No takes yet. Share an insight, caveat, or question.
Schaming et al. (2009) studied this question.
Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context: