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Structural information about the free base guanidine in the solid state could be obtained for the first time by determining the crystal structures of the 1:1 as well as the 2:1 co-crystals consisting of neutral guanidine and 2-amino-4,6-dimethyl-1,3,5-triazine using single crystal X-ray diffraction.
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Göbel et al. (2007) studied this question.
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