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Perfectly alternating copolymers can be synthesised by reacting diacrylates with terminal dienes using alternating diene metathesis polycondensation (ALTMET). This novel method is very versatile and allows preparation of diverse structures of polymers, including main‐chain liquid crystalline polymers. Main‐chain liquid crystalline polymer obtained by ALTMET. magnified image Main‐chain liquid crystalline polymer obtained by ALTMET.
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Demel et al. (2003) studied this question.
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