Synthesis and characterization of tri-titanium(iv)-1,2,3-substituted α-Keggin polyoxotungstates with heteroatoms P and Si. Crystal structure of the dimeric, Ti–O–Ti bridged anhydride form K10H2α,α-P2W18Ti6O77·17H2O and confirmation of dimeric forms in aqueous solution by ultracentrifugation molecular weight measurements†