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The effect of uniaxial orientational drawing and isometric annealing on the ratio of polymorphic modifications in the crystalline phase of poly(vinylidene fluoride) is studied. The role of drawing temperature and draw ratio in the structural rearrangements during polymer deformation is analyzed. The conditions providing the highest content of the polar crystalline phase in the polymer are determined. The mechanical properties of the films drawn at different temperatures are investigated.
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Dmitriev et al. (2006) studied this question.
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