The compound with the stoichiometry MnIII[MnIII0.2CrIII0.8(CN)6]·4H2O (1), which was prepared by slow diffusion of an aqueous solution of K3[Cr(CN)6] and a methanol solution of [Mn(saltn)]ClO4 [saltn = N,N′‐1,3‐propylenebis(salicylideneiminato) dianion] through a U‐shaped tube containing silica gel, has been characterized by elemental analysis, ICP analysis, XPS, single‐crystal X‐ray structure analysis, and magnetic measurements. The complex has a face‐centered cubic lattice analogous to Prussian blue and indicates ferrimagnetic ordering below Tc = 63 K. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)
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Shen et al. (2007) studied this question.
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