P-Substituted Ba0.95La0.05FeO3−δ as a Cathode Material for SOFCs

The need for clean and efficient energy conversion systems has stimulated tremendous research activities in the area of energy systems. Solid oxide fuel cells stand out because of their high efficiency and low emissions. In spite of the promise, to commercialize solid oxide fuel cells, the operating temperature needs to be reduced below 800 °C. Unfortunately, at such low temperatures the oxygen reduction reactions taking place at the cathode side of the solid oxide fuel cells are typically sluggish. Ferrites have recently shown that they can overcome this challenge. However, the conductivity of these materials is typically low. Here, we show by density functional theory calculations that substituting Fe in Ba 1– x La x FeO 3−δ with P lowers both the O vacancy formation and vacancy migration energies and promotes the creation of PO 4 groups. These factors contribute to improving the diffusional properties and oxygen reduction reaction performance. We further successfully introduce P in the Fe-site of Ba 0.95 La 0.05 FeO 3−δ to make a novel cathode material, Ba 0.95 La 0.05 Fe 0.95 P 0.05 O 3−δ . Consistently, we observe that Ba 0.95 La 0.05 Fe 0.95 P 0.05 O 3−δ has higher electrical conductivity and better electrocatalytic activity compared to Ba 0.95 La 0.05 FeO 3−δ . In light of these results, we suggest that nonmetal element doping is an effective strategy for the design of new ferrites.