This review surveys some aspects of the chemistry of [VCp2]. The high potential of vanadocene [VCp2] (and [V(CO)Cp2]) in organometallic chemistry is illustrated by new organometallic architectures. The rich redox chemistry of [VCp2] is shown by incorporation of this fragment into various C≡C and C≡N bonds. This molecular approach allows the connection of two (or more) paramagnetic centers through an organic linker in order to build magnetic nanoscopic organometallic wires. [VCp2] has also been studied in the field of materials such as vanadium carbide (VC) ceramics and in its role as a reducing agent toward elements of groups 8–10 to prepare Fe, Rh, and Pd colloids. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)
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Choukroun et al. (2005) studied this question.
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