The electron nuclear double resonance spectrum of 51V2+ diluted in a single crystal of MgO has been measured at 4.2° and 77°K. The spin-Hamiltonian parameters have been determined, including an additional hyperfine contribution of the type S3I. Perturbation theory up to the fourth order has been used to calculate the latter term as a result of interactions of the ground orbital singlet with higher orbital levels.
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Wijn et al. (1968) studied this question.
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