New x-ray wavelength (energy) and width measurements are reported for a number of elements from 47≤Z≤92. The x rays were produced with the use of an electron Van de Graaff, and the measurements were made with a two-axis flat-crystal transmission spectrometer equipped with angle-measuring interferometers. The new measurements reported here, combined with other high-precision x-ray wavelengths, form a moderately extensive data base for comparison with theoretical calculations. Comparison with recent revisions of a previously available all-Z calculation reveals improved patterns of general agreement with, however, important exceptions. The newly measured linewidths are in agreement with widths calculated via relativistic wave functions used for the term estimates.
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Kessler et al. (1982) studied this question.
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