Sandwich triangles: A bis([2.2]paracyclophane)tripalladium complex (1) was isolated and characterized by NMR spectroscopy, and a mixed-ligand derivative was structurally characterized. These complexes are the first isolated μ3-arene trimetal complexes of a Group 10 metal. Complex 1 undergoes facile release of a Pd0 atom (see scheme) and as such may be regarded as a Pd0 reservoir.
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Murahashi et al. (2007) studied this question.
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