The cationic osmium nitrido complexes cis- and trans-[(terpy)OsNCl2]PF6 react with 1,3-diphenylisobenzofuran at room temperature to form azavinylidene complexes by oxidative ring opening of the isobenzofuran. The reaction involves tandem electrophilic and nucleophilic reactivity at the nitrogen atom of the metal nitride.
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Seth N. Brown (1999) studied this question.
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