Jasmonic acid and its metabolites play an essential role in the regulation of plant development and systemic defense responses. Isotopically labeled standards are required to quantify plant hormones for metabolism studies using mass spectrometry. A convenient method for the preparation of deuterated analogs of jasmonates is demonstrated. Modification of commercially available methyl jasmonate by base‐catalyzed proton/deuterium exchange or Wittig reaction introduces either two or three heavy atoms into a molecule.
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Galka et al. (2005) studied this question.
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