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The C̃→à emission spectra for H2O and D2O are measured and calculated. The theoretical model is based on an exact treatment of the dissociation dynamics of the à state using a calculated potential energy surface. Agreement with the measurements is excellent. The spectra extend from λ∼380 nm up to λ∼600 nm with maxima around 425 (H2O) and 440 nm (D2O).
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Engel et al. (1987) studied this question.
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